Dorgs is really the expert, I think, but I can try to explain the process of casting for you if you want. (I'm not totally inexperienced, I've actually cast four different heads before!
)
The first thing you want to do after you've selected the HS you want to cast, is find a mold container for it.
This is the little "box" where you will put the head and pour silicone rubber around it until the head is covered.
Now just to make sure you're clear on this, silicone rubber is used to make flexible rubber molds, which are later filled with casting resin (a kind of plastic.) Both come in two liquid parts which must be mixed together and then poured before curing into solid form.
I use the term "mold box" loosely, because a lot of the time what I do, is take any old soda can, and cut off the top and bottom. This way, you just have a nice metal cylinder to use. Of course, usually this is a little too large for a head mold (might waste valuable silicone), so I cut the metal cylinder up the side, and kind of roll it a little tighter/smaller, then duct tape it on the outside so it won't come unrolled again.
Cylinders really are the best shapes for mold boxes, as you don't have any corners to fill up.
Anyway, with the soda can approach, you want to make sure the can is at least an inch taller than your head, and if you put the head inside it, the head should have about a centimeter of clearance or so.
Once you have your cylinder the right size, you're going to need a flat surface and some clay.
You want to use the clay to fill the seams between the can and whatever surface you use. The surface you attach the can to should be something smooth and non-porous, such as a plastic plate. When you pour your silicone, you don't want it leaking out that bottom edge!
You don't
have to use a soda can, you could also use any plastic container that was about the right size, including the bottom parts of McDonald's cups, among other things. Some people like to make boxes out of Lego's, all you really need is a space in which to pour the silicone around the headsculpt.
Once you've got your mold box set up, you need to assess what kind of HS you have. If it has no neck, you're going to want to sculpt one out of clay. The purpose of this is to get the head upright and stable within the mold.
You will need to smear the edges of the clay neck onto the bottom of your mold box so that it stays upright by itself. Also, the clay neck will provide a hole for you to pour your resin into later.
If your head
does have a sculpted neck already, just secure the bottom edge with a bit of clay.
Anyway, at this point you should have: an appropriately sized container with your headsculpt attached neatly inside.
Now comes the part where you actually use the silicone. You'll probably have to order some from Smooth-On or Alumilite, unless you can find some silicone rubber at your local hobby store.
The silicone comes in two parts, which must be mixed together in a ratio dictated by instructions that should come with the stuff.
You need two measuring/medicine cups and one other disposable plastic cup. One measuring cup to measure part A, one for part B, and another to mix them together in.
Once you measure out the right amount, you'll need to mix it until it seems completely homogenous/consistent in color and vicsocity. From your mixing cup, you'll need to pour the mixed silicone into your mold container.
Don't pour it
on the head itself, try to pour it down the side of the mold box, slowly letting it fill up. Keep going until the level of the silicone is at least a centimeter or so above the top of your headsculpt.
Once you're done pouring, you'll need to wait about 24 hours before removing the sculpt from the mold (depending on what brand of silicone you get, and what it's instructions actually say)
There are three ways to do this:
1 - pull the head out of the hole in the bottom of the mold (the hole created by the neck) This method leaves no seamlines when you cast the head, but may be impossible. The head might just be stuck in there, or removing it this way may cause the silicone to rip. This is only reccomended if you have the extra special flexible kind of silicone rubber.
2 - cut the mold up the back with a relatively sharp knife, but stop when you get to the top of the mold. This way you'll have a slit which you can sort of pry open, and remove the head from behind. This also means that the seamline will only go up the back of the head when casting it. (PS, you may want to mark your soda can/mold box with a Sharpie to remember where the back of your head is - you don't want seamlines running up the front of the face!)
3 - cut the mold in half. This will leave seamlines on both sides of the head, but this method could be useful for heads with a lot of detail. Also, you will need to figure out some way of lining the mold halves back up again, or else you'll never be able to cast in it.
I usually use method two.
Anyway, I hope this helps! It's kind of written off the top of my head, so I apologize if it seems kind of confusing. Feel free to ask questions, and I can write up a casting tutorial too if you'd like.
You should check around the web for molding/casting tutorials, there are some very helpful and informative ones out there.
Good luck with your casting Weezer!