Its interesting that all dios in 1/9 scale have been of characters actively fighting and within arm's reach of one another. Omitting lightsaber duels (of which I'm sure almost all will see the light of day in dio form) that gives us a number of possibilities based on that criteria.
Off the top of my head:
Old Ben vs. Walrusman
Luke vs. Sandperson
Chewie punching a Stormtrooper (Detention block)
Luke vs. Wampa
Chewie vs. Stormtroopers (Carbon Freezing Chamber)
Luke vs. Rancor
Luke vs. Boba Fett (Sarlacc)
Leia vs. Jabba
Han vs. Biker Scout
Obi-Wan and Qui Gon vs. Battle Droids
Gungans on riding beasts vs. Battle Droids
Obi-Wan vs. Jango
Mace vs. Jango
Anakin vs. Geonosians (Conveyor belt)
Anakin and Obi-Wan vs. Battle Droids (ROTS)
Obi-Wan vs. Grievous (with Boga and Bike)
Obi-Wan vs. Grievous (landing platform)
Anakin vs. Separatists
There are more of course, but I left out static encounters like Han and Greedo and those that just aren't very dynamic (like the Stormtrooper who throws the ewok.)
Off the top of my head:
Old Ben vs. Walrusman
Luke vs. Sandperson
Chewie punching a Stormtrooper (Detention block)
Luke vs. Wampa
Chewie vs. Stormtroopers (Carbon Freezing Chamber)
Luke vs. Rancor
Luke vs. Boba Fett (Sarlacc)
Leia vs. Jabba
Han vs. Biker Scout
Obi-Wan and Qui Gon vs. Battle Droids
Gungans on riding beasts vs. Battle Droids
Obi-Wan vs. Jango
Mace vs. Jango
Anakin vs. Geonosians (Conveyor belt)
Anakin and Obi-Wan vs. Battle Droids (ROTS)
Obi-Wan vs. Grievous (with Boga and Bike)
Obi-Wan vs. Grievous (landing platform)
Anakin vs. Separatists
There are more of course, but I left out static encounters like Han and Greedo and those that just aren't very dynamic (like the Stormtrooper who throws the ewok.)
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